Dissociative electron transfer of copper(ii) complexes of glycyl(glycyl/alanyl)tryptophanin vacuo: IRMPD action spectroscopy provides evidence of transition from zwitterionic to non-zwitterionic peptide structures

Author:

Li Yinan1234,Li Mengzhu1234,Spencer Daniel M.1234ORCID,Lau Justin Kai-Chi56789ORCID,Martens Jonathan1011121314ORCID,Berden Giel1011121314ORCID,Oomens Jos1011121314ORCID,Fang De-Cai1516174ORCID,Hopkinson Alan C.5678,Siu K. W. Michael56789,Siu Chi-Kit118194ORCID,Chu Ivan K.1234ORCID

Affiliation:

1. Department of Chemistry

2. The University of Hong Kong

3. Pokfulam

4. China

5. Department of Chemistry and Centre for Research in Mass Spectrometry

6. York University

7. Toronto

8. Canada

9. Department of Chemistry and Biochemistry

10. Radboud University

11. Institute for Molecules and Materials

12. FELIX Laboratory

13. 6525 ED Nijmegen

14. The Netherlands

15. College of Chemistry

16. Beijing Normal University

17. Beijing 100875

18. City University of Hong Kong

19. Kowloon Tong

Abstract

Non-zwitterionic π-centered [GGWπ+is formed from zwitterionic [CuII(dien)GGW]˙2+through dissociative one-electron transfer involving proton and unpaired electron migrations.

Funder

Natural Sciences and Engineering Research Council of Canada

Research Grants Council, University Grants Committee

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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