Water-promoted defluorinative synthesis of fluoroalkylated 1,5-diazapentadienes by using (NH4)2CO3 as an NH2 and NH source-Reference-Cited by-同舟云学术

Water-promoted defluorinative synthesis of fluoroalkylated 1,5-diazapentadienes by using (NH₄)₂CO₃ as an NH₂ and NH source

Published:2023 Issue:23 Volume:25 Page:9672-9679
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Han Wei¹,Chen Yu-Lan¹,Tang Xi¹,Zhou Jie²,Ma Mengtao³^ORCID,Shen Zhi-Liang¹^ORCID,Chu Xue-Qiang¹^ORCID

Affiliation:

1. Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China

2. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing 211816, China

3. Department of Chemistry and Materials Science, College of Science, Nanjing Forestry University, Nanjing 210037, China

Abstract

A H2O-promoted and (NH4)2CO3-enabled defluoroiminization reaction of fluoroalkyl alkenes for the synthesis of fluoroalkylated 1,5-diazapentadienes has been developed.

Funder

National Natural Science Foundation of China

Nanjing Tech University

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/GC/D3GC03717G

Reference62 articles.

1. 1-Azadienes in cycloaddition and multicomponent reactions towards N-heterocycles