Sequential alcohol oxidation/putative homo Claisen–Tishchenko-type reaction to give esters: a key process in accessing novel biologically active lactone macrocycles

Author:

Viana Hugo12345,Carreiro Elisabete P.12345,Goth Albertino12345,Bacalhau Patrícia12345,Caldeira Ana Teresa12345,Martins Maria do Rosário12345,Burke Anthony Joseph12345

Affiliation:

1. Centro de Química de Évora

2. Institute for Research and Advanced Studies (IIFA)

3. University of Évora

4. 7000 Évora

5. Portugal

Abstract

We report an efficient methodology for the direct oxidative esterification of primary alcohols to diether-esters using pyridinium chlorochromate (PCC).

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference46 articles.

1. J. Otera and J.Nishikido, Esterification: methods, reactions, and applications, Wiley – VCH, Weinheim, 2nd edn, 2010

2. Direct oxidative esterification of alcohols

3. Transesterification

4. R. C. Larock , Comprehensive organic transformations: a guide to functional group preparations, Wiley – VCH, New York, 2nd edn, 1999

5. Chemicals from Renewables: Aerobic Oxidation of Furfural and Hydroxymethylfurfural over Gold Catalysts

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