Stabilization of a high-spin three-coordinate Fe(<scp>iii</scp>) imidyl complex by radical delocalization-Reference-Cited by-同舟云学术

Stabilization of a high-spin three-coordinate Fe(iii) imidyl complex by radical delocalization

Published:2022 Issue:33 Volume:13 Page:9637-9643
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Yang Po-Chun¹,Yu Kuan-Po¹,Hsieh Chi-Tien¹,Zou Junjie²,Fang Chia-Te¹,Liu Hsin-Kuan³^ORCID,Pao Chih-Wen⁴,Deng Liang²,Cheng Mu-Jeng¹^ORCID,Lin Chun-Yi¹^ORCID

Affiliation:

1. Department of Chemistry, National Cheng Kung University, No. 1 University Road, Tainan 701014, Taiwan

2. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. China

3. Core Facility Center, National Cheng Kung University, No. 1 University Road, Tainan 701014, Taiwan

4. National Synchrotron Radiation Research Center, 101 Hsin-Ann Road, Hsinchu 300092, Taiwan

Abstract

A stable three-coordinate Fe imido radical (i.e. imidyl) complex can be stabilized via N radical delocalization onto the aryl imido substituent.

Funder

Ministry of Science and Technology, Taiwan

National Cheng Kung University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link