Mononuclear Fe(<scp>iii</scp>) complexes with 2,4-dichloro-6-((quinoline-8-ylimino)methyl)phenolate: synthesis, structure, and magnetic behavior-Reference-Cited by-同舟云学术

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Mononuclear Fe(iii) complexes with 2,4-dichloro-6-((quinoline-8-ylimino)methyl)phenolate: synthesis, structure, and magnetic behavior

Published:2024 Issue:15 Volume:53 Page:6809-6817
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jeong Ah Rim¹,Park Si Ra²,Shin Jong Won¹,Kim Jihyun²,Tokunaga Ryuya³,Hayami Shinya³^ORCID,Min Kil Sik²^ORCID

Affiliation:

1. Department of Chemistry, Kyungpook National University, Daegu 41566, Republic of Korea

2. Department of Chemistry Education, Kyungpook National University, Daegu 41566, Republic of Korea

3. Department of Chemistry, Kumamoto University, Kumamoto 860-8555, Japan

Abstract

We synthesized three Fe(iii) mononuclear complexes and investigated the effects of the functional group of qsal ligands and anions on spin crossover behaviors and the relaxation times of T1 and T2 in DMF solution.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT04385A

Reference56 articles.

1. Manipulating Spin Transition To Achieve Switchable Multifunctions

2. Supramolecular Tuning of Spin Crossover Properties in Isostructural Cocrystal Solvates

3. Chemical Manipulation of the Spin-Crossover Dynamics through Judicious Metal-Ion Dilution

4. Hysteretic Spin Crossover with High Transition Temperatures in Two Cobalt(II) Complexes

5. Investigation of the unique magnetic behaviours of isomers in a 1,2-dithiooxalato-bridged diiron(ii) complex

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