Homoleptic borates and aluminates containing the difluorophosphato ligand – [M(O2PF2)x]y− – synthesis and characterization-Reference-Cited by-同舟云学术

Homoleptic borates and aluminates containing the difluorophosphato ligand – [M(O2PF2)x]y− – synthesis and characterization

Published:2015 Issue:15 Volume:44 Page:7048-7057
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Schulz Christoph¹²³⁴,Eiden Philipp¹²³⁴,Klose Petra¹²³⁴,Ermantraut Andreas¹²³⁴,Schmidt Michael⁵⁶⁴,Garsuch Arnd⁵⁶⁴,Krossing Ingo¹²³⁴

Affiliation:

1. Institut für Anorganische und Analytische Chemie and Freiburger Materialforschungszentrum (FMF)

2. Universität Freiburg

3. 79104 Freiburg

4. Germany

5. BASF SE

6. Ludwigshafen

Abstract

A new class of WCAs…? The difluoro-phosphato ligand (O₂PF₂) was used for the synthesis of borates and aluminates of the [M(O₂PF₂)_x]^y−-type in order to generate weakly coordinating anions.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00469A

Reference58 articles.

1. Reactions of boron compounds with difluorophosphoric acid; characterisation of the tetrakis(difluorophosphato)borate anion by multinuclear (11B, 19F, and 31P) nuclear magnetic resonance spectroscopy

2. Noncoordinating Anions—Fact or Fiction? A Survey of Likely Candidates

3. Chemistry with weakly-coordinating fluorinated alkoxyaluminate anions: Gas phase cations in condensed phases?

4. THE ISOLATION OF THE ICOSAHEDRAL B12H12-2 ION

5. .eta.1-Benzene coordination: the synthesis and x-ray crystal structure of a novel silver salt of the weakly coordinating carborane anion B11CH12-

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