An investigation on the chemistry of the R2PP ligand: reactions of a phosphanylphosphinidene complex of tungsten(vi) with electrophilic reagents
Author:
Affiliation:
1. Chemical Faculty
2. Department of Inorganic Chemistry
3. Gdansk University of Technology
4. Pl-80-233 Gdansk
5. Poland
6. Institut für Anorganische Chemie
7. Universität Stuttgart
8. 70550 Stuttgart
9. Germany
Abstract
The nucleophilic properties of the title compound [(2,6-i-Pr2C6H3N)2(Cl)W(η2-t-Bu2PP)]Li·3DME (1) were investigated in reactions with selected electrophilic reagents such as MeI, M(CO)5THF (M = Cr, Mo, W), AlCl3, and GaCl3.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT03085D
Reference49 articles.
1. A new synthetic entry to phosphinophosphinidene complexes. Synthesis and structural characterisation of the first side-on bonded and the first terminally bonded phosphinophosphinidene zirconium complexes [μ-(1,2∶2-η-tBu2PP){Zr(Cl)Cp2}2] and [{Zr(PPhMe2)Cp2}(η1-P–PtBu2)]
2. Syntheses and structures of the first terminal phosphanylphosphido complex of hafnium [Cp2Hf(Cl){η1-(Me3Si)P–P(NEt2)2}] and the first zirconocene-phosphanylphosphinidene dimer [Cp2Zr{μ2-P–P(NEt2)2}2ZrCp2]
3. Bildung und Struktur von [μ-(1,2 : 2-η-tBu2P-P){Mo(CO)2cp′}2]
4. Reaktionen des [η2-{P-PtBu2}Pt(PPh3)2] und [η2-{P-PtBu2}Pt(dppe)] mit Metallcarbonylen. Bildung von [η2-{(CO)5M · PPtBu2}Pt(PPh3)2] (M = Cr, W) und [η2-{(CO)5Cr · PPtBu2}Pt(dppe)]
5. Komplexchemie P-reicher Phosphane und Silylphosphane. XIV. PhosphinophosphinidentBu2P?P als Ligand in den Pt-Komplexen [?2-{tBu2P?P}Pt(PPh3)2] und [?2-{tBu2P?P}Pt(PEtPh2)2]
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