An investigation on the chemistry of the R2PP ligand: reactions of a phosphanylphosphinidene complex of tungsten(vi) with electrophilic reagents-Reference-Cited by-同舟云学术

An investigation on the chemistry of the R2PP ligand: reactions of a phosphanylphosphinidene complex of tungsten(vi) with electrophilic reagents

Published:2016 Issue:5 Volume:45 Page:2172-2179
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Grubba Rafał¹²³⁴⁵,Ordyszewska Anna¹²³⁴⁵,Ponikiewski Łukasz¹²³⁴⁵,Gudat Dietrich⁶⁷⁸⁹,Pikies Jerzy¹²³⁴⁵

Affiliation:

1. Chemical Faculty

2. Department of Inorganic Chemistry

3. Gdansk University of Technology

4. Pl-80-233 Gdansk

5. Poland

6. Institut für Anorganische Chemie

7. Universität Stuttgart

8. 70550 Stuttgart

9. Germany

Abstract

The nucleophilic properties of the title compound [(2,6-i-Pr₂C₆H₃N)₂(Cl)W(η²-t-Bu₂PP)]Li·3DME (1) were investigated in reactions with selected electrophilic reagents such as MeI, M(CO)₅THF (M = Cr, Mo, W), AlCl₃, and GaCl₃.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT03085D

Reference49 articles.

1. A new synthetic entry to phosphinophosphinidene complexes. Synthesis and structural characterisation of the first side-on bonded and the first terminally bonded phosphinophosphinidene zirconium complexes [μ-(1,2∶2-η-tBu2PP){Zr(Cl)Cp2}2] and [{Zr(PPhMe2)Cp2}(η1-P–PtBu2)]

2. Syntheses and structures of the first terminal phosphanylphosphido complex of hafnium [Cp2Hf(Cl){η1-(Me3Si)P–P(NEt2)2}] and the first zirconocene-phosphanylphosphinidene dimer [Cp2Zr{μ2-P–P(NEt2)2}2ZrCp2]

3. Bildung und Struktur von [μ-(1,2 : 2-η-tBu2P-P){Mo(CO)2cp′}2]

4. Reaktionen des [η2-{P-PtBu2}Pt(PPh3)2] und [η2-{P-PtBu2}Pt(dppe)] mit Metallcarbonylen. Bildung von [η2-{(CO)5M · PPtBu2}Pt(PPh3)2] (M = Cr, W) und [η2-{(CO)5Cr · PPtBu2}Pt(dppe)]

5. Komplexchemie P-reicher Phosphane und Silylphosphane. XIV. PhosphinophosphinidentBu2P?P als Ligand in den Pt-Komplexen [?2-{tBu2P?P}Pt(PPh3)2] und [?2-{tBu2P?P}Pt(PEtPh2)2]

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