Halide-free neodymium phosphate based catalyst for highly cis-1,4 selective polymerization of dienes

Author:

Ren Yixin1234,Miller Justin T.1234,Polderman Stefanie T.1234,Vo Trinh D.1234,Wallace Adele C. M.1234,Cue John Michael O.1234,Tran Sarah T.1234,Biewer Michael C.1234,Stefan Mihaela C.12345ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. The University of Texas at Dallas

3. Richardson

4. USA

5. Department of Bioengineering

Abstract

[Nd(μ-DEP)3]x/TIBA stereospecifically polymerizes myrcene in a pseudo-living Ziegler–Natta like catalytic system despite the absence of a halide.

Funder

Welch Foundation

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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