Cycloaddition of CO2 to epoxides “around water”: a strategy to apply and recycle efficient water-soluble bio-based organocatalysts in biphasic media

Author:

Theerathanagorn Tharinee1,Vidal-López Anna23,Comas-Vives Aleix24ORCID,Poater Albert3ORCID,D′ Elia Valerio1ORCID

Affiliation:

1. Department of Materials Science and Engineering, VISTEC Advanced Laboratory for Environment-Related Inorganic and Organic Syntheses, Vidyasirimedhi Institute of Science and Technology, (VISTEC), 21210, Payupnai, Wang Chan, Thailand

2. Department of Chemistry, Universitat Autònoma de Barcelona, 08193 Cerdanyola del Vallès, Catalonia, Spain

3. Institut de Química Computacional i Catàlisi and Departament de Química, Universitat de Girona, C/Maria Aurèlia Capmany 69, 17003 Girona, Catalonia, Spain

4. Institute of Materials Chemistry, TU Wien, 1060 Wien, Austria

Abstract

A biphasic reaction approach is presented for the cycloaddition of CO2 to epoxides where the catalyst is dissolved in water droplets and the reaction occurs at the aqueous–organic interface allowing easy recycling of the catalyst by decantation.

Funder

Ministerio de Ciencia e Innovación

National Research Council of Thailand

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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