CO2 Valorization in Deep Eutectic Solvents

Author:

Guo Zhenbo1,Zhang Zhicheng1,Huang Yuchen1,Lin Tianxing1,Guo Yixin1,He Liang‐Nian1,Liu Tianfei123ORCID

Affiliation:

1. State Key Laboratory of Elemento-organic Chemistry College of Chemistry Nankai University Weijin Road No. 94 Tianjin 300071 China

2. Haihe Laboratory of Sustainable Chemical Transformations Tianjin 300192 China

3. Key Laboratory of Organofluorine Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai 200032 China

Abstract

AbstractThe deep eutectic solvent (DES) has emerged in recent years as a valuable medium for converting CO2 into valuable chemicals because of its easy availability, stability, and safety, and its capability to dissolve carbon dioxide. CO2 valorization in DES has evolved rapidly over the past 20 years. As well as being used as solvents for acid/base‐promoted CO2 conversion for the production of cyclic carbonates and carbamates, DESs can be used as reaction media for electrochemical CO2 reduction for formic acid and CO. Among these products, cyclic carbonates can be used as solvents and electrolytes, carbamate derivatives include the core structure of many herbicides and pesticides, and formic acid and carbon monoxide, the C1 electrochemical products, are essential raw materials in the chemical industries. An overview of the application of DESs for CO2 valorization in recent years is presented in this review, followed by a compilation and comparison of product types and reaction mechanisms within the different types of DESs, and an outlook on how CO2 valorization will be developed in the future.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Wiley

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