Photoisomerization of phytochrome chromophore models: an XMS-CASPT2 study-Reference-Cited by-同舟云学术

Photoisomerization of phytochrome chromophore models: an XMS-CASPT2 study

Published:2022 Issue:48 Volume:24 Page:29393-29405
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Rao Aditya G.¹^ORCID,Schapiro Igor¹^ORCID

Affiliation:

1. Fritz Haber Center for Molecular Dynamics Research, Institute of Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel

Abstract

The photoisomerization was studied for truncated phytochrome chromophore models. Addition of functional groups was found to alter the excited state potential energy surface. The isomerization mechanism changes from hula twist to one bond flip.

Funder

H2020 European Research Council

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP04249E

Reference54 articles.

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5. Photoconversion Mechanism of a Green/Red Photosensory Cyanobacteriochrome AnPixJ: Time-Resolved Optical Spectroscopy and FTIR Analysis of the AnPixJ-GAF2 Domain

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