O2 activation at a trispyrazolylborato nickel(ii) malonato complex
Author:
Affiliation:
1. Institut für Chemie
2. Humboldt-Universität zu Berlin
3. 12489 Berlin
4. Germany
Abstract
On moving from an iron(ii) to an analogous nickel(ii) malonate complex the reaction with O2 changes from C–C bond cleavage to hydroxylation.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT04056C
Reference17 articles.
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3. Electronic Substituent Effects on the Cleavage Specificity of a Non-Heme Fe2+-Dependent β-Diketone Dioxygenase and Their Mechanistic Implications
4. Reaction Coordinate Analysis for β-Diketone Cleavage by the Non-Heme Fe2+-Dependent Dioxygenase Dke1
5. Spectroscopic and Computational Studies of α-Keto Acid Binding to Dke1: Understanding the Role of the Facial Triad and the Reactivity of β-Diketones
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