Ring-expanded N-heterocyclic carbenes as ligands in iron-catalysed cross-coupling reactions of arylmagnesium reagents and aryl chlorides-Reference-Cited by-同舟云学术

Ring-expanded N-heterocyclic carbenes as ligands in iron-catalysed cross-coupling reactions of arylmagnesium reagents and aryl chlorides

Published:2018 Issue:47 Volume:54 Page:6044-6047
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Teng Qiaoqiao¹²³⁴⁵,Wu Wenqin⁶⁷⁸⁵,Duong Hung A.⁶⁷⁸⁵^ORCID,Huynh Han Vinh¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. National University of Singapore

3. 3 Science Drive 3

4. Singapore 117543

5. Singapore

6. Institute of Chemical and Engineering Sciences (ICES)

7. Agency for Science, Technology and Research (A*STAR), 8, Biomedical Grove, Neuros, #07-01

8. Singapore 138665

Abstract

Modulation of the steric bulk of N-heterocyclic carbenes by altering the ring size and N-substituents, and their performance in iron-catalysed cross-coupling reactions.

Funder

Economic Development Board - Singapore

Institute of Chemical and Engineering Sciences

National University of Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC01808A

Reference45 articles.

1. 1,3-Dialkyl- and 1,3-Diaryl-3,4,5,6-tetrahydropyrimidin-2-ylidene Rhodium(i) and Palladium(II) Complexes: Synthesis, Structure, and Reactivity

2. Rh(1,3-bis(2,4,6-trimethylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)(COD) tetrafluoroborate, an unsymmetrical Rh-homoazallylcarbene: synthesis, X-ray structure and reactivity in carbonyl arylation and hydrosilylation reactions

3. Active catalysts for the Suzuki coupling: Palladium complexes of tetrahydropyrimid-2-ylidenes

4. Expanded ring and functionalised expanded ring N-heterocyclic carbenes as ligands in catalysis

5. Donor‐Functionalised Expanded Ring N‐Heterocyclic Carbenes: Highly Effective Ligands in Ir‐Catalysed Transfer Hydrogenation

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