A mechanistic study on the gold(i)-catalyzed cyclization of propargylic amide: revealing the impact of expanded-ring N-heterocyclic carbenes-Reference-Cited by-同舟云学术

A mechanistic study on the gold(i)-catalyzed cyclization of propargylic amide: revealing the impact of expanded-ring N-heterocyclic carbenes

Published:2022 Issue:2 Volume:12 Page:674-685
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Ma Yumiao¹²^ORCID,Ali Hafiz Saqib³^ORCID,Hussein Aqeel A.⁴^ORCID

Affiliation:

1. BSJ Institute, Haidian, Beijing, 100084, People's Republic of China

2. Hangzhou Yanqu Information Technology Co., Ltd., Xixi Legu Creative Pioneering Park, No. 712 Wen'er West Road, Xihu District, Hangzhou City, Zhejiang Province, 310003, People's Republic of China

3. School of Chemistry, University of Edinburgh, Joseph Black Building, David Brewster Rd, Kings Buildings, EH9 3FJ Edinburgh, UK

4. Department of Pharmacy, College of Medicine, Komar University of Science and Technology, Sulaymaniyah, Kurdistan Region, Iraq

Abstract

Density functional theory (DFT) was applied to understand the mechanistic pathway of the gold(i)-catalyzed cyclization of propargylic amide, and to reveal the impact of expanded-ring N-heterocyclic carbenes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CY/D1CY01617B

Reference121 articles.

1. Cationic Gold(I) Complexes: Highly Efficient Catalysts for the Addition of Alcohols to Alkynes

2. Highly Efficient AuI-Catalyzed Hydration of Alkynes

3. Reversible C−F Bond Formation and the Au-Catalyzed Hydrofluorination of Alkynes

4. Carbocyclisation of alkynes with external nucleophiles catalysed by gold, platinum and other electrophilic metals

5. Recent advances in syntheses of carbocycles and heterocycles via homogeneous gold catalysis. Part 2: Cyclizations and cycloadditions

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