Applications of the Marcus cross relation to inner sphere reduction of O2: implications in small-molecule activation-Reference-Cited by-同舟云学术

Applications of the Marcus cross relation to inner sphere reduction of O2: implications in small-molecule activation

Published:2019 Issue:9 Volume:6 Page:2396-2403
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Lacy David C.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. University at Buffalo

3. State University of New York

4. Buffalo

5. USA

Abstract

The Marcus cross relation is demonstrated to be applicable to inner sphere electron transfer from iron to molecular oxygen by incorporation of the Fe(iii)–O₂ to Fe(iii) + superoxide BDFE in K_eq. A few case-studies are provided as working examples.

Funder

University at Buffalo

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QI/C9QI00828D

Reference63 articles.

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