Electrochemical approach of the reductive activation of O<sub>2</sub> by a nonheme Fe<sup>II</sup> complex. Some clues for the development of catalytic oxidations-Reference-Cited by-同舟云学术

Electrochemical approach of the reductive activation of O₂ by a nonheme Fe^II complex. Some clues for the development of catalytic oxidations

Published:2024 Issue: Volume: Page:
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bohn Antoine¹,Robinson Amanda Lyn¹,Sénéchal-David Katell¹,Herrero Christian¹,Kanoufi Frédéric²^ORCID,Anxolabéhère-Mallart Elodie³^ORCID,Banse Frédéric¹^ORCID

Affiliation:

1. Université Paris-Saclay, CNRS, Institut de Chimie Moléculaire et des Matériaux d'Orsay, 91400, Orsay, France

2. Interfaces, Traitements, Organisation et Dynamique des Systèmes, Université de Paris, CNRS, F-75013 Paris, France

3. Laboratoire d'Electrochimie Moléculaire, Université de Paris, CNRS, F-75013 Paris, France

Abstract

Reductive activation of O2 by an FeII complex at −650 mV vs. SCE yields an FeIII peroxo intermediate and ultimately the oxidative bromination of anisole. This reaction is in competition with the direct reduction of the reaction intermediate.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01870B

Reference71 articles.

1. J. H.Teles , W.Partenheimer , R.Jira , F.Cavani , G.Strukul , R.Hage , J. W.Boer , L.Gooßen , P.Mamone and O. A.Kholdeeva , Oxidation , in Applied Homogeneous Catalysis with Organometallic Compounds: A Comprehensive Handbook in Four Volumes, Third Edition , Wiley , 1st edn, 2017 , vol. 64

2. The Production of Propene Oxide: Catalytic Processes and Recent Developments

3. Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations

4. Sustainability in Catalytic Oxidation: An Alternative Approach or a Structural Evolution?