Formic acid catalyzed isomerization of protonated cytosine: a lower barrier reaction for tautomer production of potential biological importance-Reference-Cited by-同舟云学术

Formic acid catalyzed isomerization of protonated cytosine: a lower barrier reaction for tautomer production of potential biological importance

Published:2017 Issue:21 Volume:19 Page:13515-13523
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Jin Lingxia¹²³⁴⁵^ORCID,Lv Mengdan¹²³⁴⁵,Zhao Mengting¹²³⁴⁵,Wang Rui¹²³⁴⁵,Zhao Caibin¹²³⁴⁵,Lu Jiufu¹²³⁴⁵,Wang Ling¹²³⁴⁵,Wang Wenliang⁶⁷⁸⁹⁵^ORCID,Wei Yawen¹⁰¹¹¹²⁵

Affiliation:

1. Shaanxi Key Laboratory of Catalysis

2. School of Chemical & Environment Science

3. Shaanxi Sci-Tech University

4. Hanzhong 723001

5. China

6. Key Laboratory for Macromolecular Science of Shaanxi Province

7. School of Chemistry and Chemical Engineering

8. Shaanxi Normal University

9. Xi'an 710062

10. Institute of publication Science

11. Chang'an University

12. Xi'an 710064

Abstract

Isomerization barrier for isolated unimolecular reaction is quite high, and its probability may be very small. Reduction of isomerization barrier is over 36 kJ mol⁻¹ in going from H₂O to HCOOH⋯H₂O group catalysts.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP01008G

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