Structural and kinetic investigation of the hydride composite Ca(BH4)2 + MgH2 system doped with NbF5 for solid-state hydrogen storage

Author:

Karimi Fahim123,Klaus Pranzas P.123,Pistidda Claudio123,Puszkiel Julián A.12345,Milanese Chiara678910,Vainio Ulla1231112,Paskevicius Mark13141516,Emmler Thomas123,Santoru Antonio123,Utke Rapee1231718,Tolkiehn Martin11123,Minella Christian B.123,Chaudhary Anna-Lisa123,Boerries Stefan123,Buckley Craig E.13141516,Enzo Stefano1920212223,Schreyer Andreas123,Klassen Thomas123,Dornheim Martin123

Affiliation:

1. Helmholtz-Zentrum Geesthacht

2. 21502 Geesthacht

3. Germany

4. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) and Centro Atómico Bariloche – Av. Bustillo 9500

5. S. C. de Bariloche

6. Pavia Hydrogen Lab

7. C.S.G.I. & Chemistry Department

8. Physical Chemistry Section

9. University of Pavia

10. 27100 Pavia

11. HASYLAB at DESY

12. D-22603 Hamburg

13. Department of Imaging and Applied Physics

14. Curtin University

15. Perth WA 6845

16. Australia

17. School of Chemistry

18. Institute of Science

19. Nanosized Materials and Mechanochemistry

20. Department of Chemistry and Pharmacy

21. University of Sassari

22. 07100 Sassari

23. Italy

Abstract

NbF5 reduces dehydrogenation temperature of Ca(BH4)2 + MgH2 system by 100 °C. Here, we give a possible elucidation of this effect.

Funder

Bundesministerium für Bildung und Forschung

The University of Western Australia

German Academic Exchange Service

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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