Chemical fixation of CO2 into cyclic carbonates by azo-containing Schiff base metal complexes

Author:

İkiz Mesut1234,İspir Esin1234,Aytar Emine1564,Ulusoy Mahmut1564,Karabuğa Şemistan1234,Aslantaş Mehmet78294,Çelik Ömer1011124

Affiliation:

1. Department of Chemistry

2. Kahramanmaraş Sütçü İmam University

3. Kahramanmaraş 46050–9

4. Turkey

5. Harran University

6. Şanlıurfa 63190

7. Physics Department

8. Science and Arts Faculty

9. 46100 Kahramanmaraş

10. Science and Technology Application and Research Center

11. Dicle University

12. 21280 Diyarbakır

Abstract

Two new azo-containing Schiff bases and their transition metal complexes were synthesized. Single-crystal X-ray analyses were performed on the ligand (L1H) and complex (Zn(L1)2). The synthesized metal complexes were used as catalysts for the chemical fixation of CO2 into cyclic carbonates. The azo moiety increased the activity.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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