Pd-Promoted cross coupling of iodobenzene with vinylgold via an unprecedented phenyl transmetalation from Pd to Au-Reference-Cited by-同舟云学术

Pd-Promoted cross coupling of iodobenzene with vinylgold via an unprecedented phenyl transmetalation from Pd to Au

Published:2020 Issue:46 Volume:56 Page:6213-6216
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wang Jiwei¹²³⁴⁵,Zhan Licheng¹²³⁴⁵,Wang Gendi¹²³⁴⁵,Wei Yin⁶⁷⁸⁹¹⁰^ORCID,Shi Min¹²³⁴⁵,Zhang Jun¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering

2. Feringa Nobel Prize Scientist Joint Research Center

3. School of Chemistry and Molecular Engineering

4. East China University of Science and Technology

5. Shanghai 200237

6. State Key Laboratory of Organometallic Chemistry

7. Shanghai Institute of Organic Chemistry

8. Chinese Academy of Sciences

9. Shanghai 200032

10. China

Abstract

Oxidative addition of Pd/Au vinylene species with iodobenzene reveals the effect of a strong metallophilic Pd⋯Au interaction on phenyl transmetalation from Pd^IV to Au^I, which allows subsequent reductive elimination of LAuI at Pd and Au.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC02645J

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