Stability of metal–metal interactions in transmetallation intermediates based on electronics of bridging arene ligands determined through pyridine titrations-Reference-Cited by-同舟云学术

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Stability of metal–metal interactions in transmetallation intermediates based on electronics of bridging arene ligands determined through pyridine titrations

Published:2024 Issue: Volume: Page:
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Marghalani Rana¹^ORCID,Cueny Eric S.¹^ORCID

Affiliation:

1. Department of Chemistry, Boston University, 590 Commonwealth Ave., Boston, MA 02215, USA

Abstract

Herein, we compare the known dinuclear complex [(CNC)(PPh3)Pt–Au(PPh3)]+ (2) with the newly synthesized [(CNCF)(PPh3)Pt–Au(PPh3)]+ (2-F). We use pyridine titrations to establish the relative thermodynamic stability of 2vs.2-F.

Funder

Boston University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01828A

Reference49 articles.

1. Transmetalation of Unsaturated Carbon Nucleophiles from Boron-Containing Species to the Mid to Late d-Block Metals of Relevance to Catalytic C−X Coupling Reactions (X = C, F, N, O, Pb, S, Se, Te)

2. Transmetallation of alkynyl and aryl complexes of Group 10 transition metals

3. Transmetalation of boronic acids and their derivatives: mechanistic elucidation and relevance to catalysis

4. Reaction Mechanism of Transmetalation between Tetraorganostannanes and Platinum(II) Aryltriflate Complexes. Mechanistic Model for Stille Couplings

5. Transmetalation, Involving Organotin Aryl, Thiolate, and Amide Compounds. An Unusual Type of Dissociative Ligand Substitution Reaction

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