Copper-catalyzed defluorinative arylboration of vinylarenes with polyfluoroarenes-Reference-Cited by-同舟云学术

Copper-catalyzed defluorinative arylboration of vinylarenes with polyfluoroarenes

Published:2023 Issue:9 Volume:14 Page:2342-2347
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wu Fu-Peng¹,Gu Xing-Wei¹,Geng Hui-Qing¹,Wu Xiao-Feng¹²^ORCID

Affiliation:

1. Leibniz-Institut für Katalyse e.V., Albert-Einstein-Straße 29a, 18059 Rostock, Germany

2. Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 116023, Dalian, Liaoning, China

Abstract

Catalyzed by CuCl and DPEphos, various β-polyfluoroaryl boronates were obtained from styrenes and polyfluoroarenes via defluorinative arylboration. With the use of a chiral ligand, the first example of chiral version was realized.

Funder

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC06472C

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