Carbon dioxide reduction by an Al–O–P frustrated Lewis pair-Reference-Cited by-同舟云学术

Carbon dioxide reduction by an Al–O–P frustrated Lewis pair

Published:2022 Issue:27 Volume:13 Page:8088-8094
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wickemeyer Lucas¹^ORCID,Aders Niklas¹,Mix Andreas¹,Neumann Beate¹,Stammler Hans-Georg¹^ORCID,Cabrera-Trujillo Jorge J.²^ORCID,Fernández Israel²^ORCID,Mitzel Norbert W.¹^ORCID

Affiliation:

1. Lehrstuhl für Anorganische Chemie und Strukturchemie, Centrum für Molekulare Materialen CM2, Fakultät für Chemie, Universität Bielefeld, Universitätsstraße 25, Bielefeld 33615, Germany

2. Departamento de Química Orgánica I, Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Madrid 28040, Spain

Abstract

Addition vs. reduction: the geminal FLP Bis2Al–O–PtBu2 can reversibly bind molecular hydrogen, it reacts with CO2 to give an adduct, and its hydrogen adduct reduces CO2 to an adduct of formic acid.

Funder

Deutsche Forschungsgemeinschaft

Ministerio de Ciencia e Innovación

Agencia Estatal de Investigación

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC01870E

Reference55 articles.

1. Fluoride Ion Chelation By a Bidentate Phosphonium/Borane Lewis Acid