Synthesis of ethylene–norbornene–1-octene terpolymers with high 1-octene contents, molar masses, and tunable Tg values, in high yields using half-titanocene catalysts-Reference-Cited by-同舟云学术

Synthesis of ethylene–norbornene–1-octene terpolymers with high 1-octene contents, molar masses, and tunable Tg values, in high yields using half-titanocene catalysts

Published:2021 Issue:30 Volume:12 Page:4372-4383
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Boggioni Laura¹²³⁴^ORCID,Harakawa Hitoshi⁵⁶⁷⁸,Losio Simona¹²³⁴^ORCID,Nomura Kotohiro⁵⁶⁷⁸^ORCID,Tritto Incoronata¹²³⁴^ORCID

Affiliation:

1. Istituto di Scienze e Tecnologie Chimiche “G. Natta”

2. Consiglio Nazionale delle Ricerche

3. 20133 Milano

4. Italy

5. Department of Chemistry

6. Tokyo Metropolitan University

7. Tokyo 192-0397

8. Japan

Abstract

Synthesis of unique poly(E-ter–N-ter–O)s using half-titanocene catalysts: 1-octene does not behave as a chain termination/transfer agent unlike ansa-metallocenes.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2021/PY/D1PY00647A

Reference51 articles.

1. Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts

2. Metallocenes for polymer catalysis

3. Group 4 ansa-Cyclopentadienyl-Amido Catalysts for Olefin Polymerization