Metastable properties of a garnet type Li5La3Bi2O12 solid electrolyte towards low temperature pressure driven densification

Author:

Campanella Daniele12ORCID,Krachkovskiy Sergey1ORCID,Bertoni Giovanni3ORCID,Gazzadi Gian Carlo3,Golozar Maryam4,Kaboli Shirin1,Savoie Sylvio1,Girard Gabriel1,Gheorghe Nita Alina Cristina1,Okhotnikov Kirill5ORCID,Feng Zimin1,Guerfi Abdelbast1,Vijh Ashok1,Gauvin Raynald4,Bélanger Daniel2ORCID,Paolella Andrea16ORCID

Affiliation:

1. Centre d'Excellence en Électrification des Transports et Stockage d'Énergie, Hydro-Québec, 1806 Boulevard Lionel-Boulet, Varennes, Québec, J3X 1S1, Canada

2. Université du Québec à Montréal (UQAM), Département de Chimie, 2101 Rue Jeanne-Mance, Montréal, Québec, H3C 3P8, Canada

3. Istituto Nanoscienze, Consiglio Nazionale delle Ricerche, Via Campi 213/A, 41125 Modena, Italy

4. McGill University, Mining & Materials Engineering Department, 3610 University Street, Montréal, Québec, H3A 0C5, Canada

5. Independent Researcher, 31-421 Reduta 38/9, Kraków, Poland

6. Austrian Institute of Technology, Battery Technologies, Giefinggasse 2, 1210, Wien, Austria

Abstract

Hot-pressing leads to low temperature densification of garnet type Li5La3Bi2O12 solid electrolyte and density functional theory calculations allow to explore its metastable properties under the formation of impurities.

Funder

Hydro-Québec

Mitacs

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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