Design and synthesis of a nonlinear optical material BaAl4S7with a wide band gap inspired from SrB4O7

Author:

Mei Dajiang1234,Jiang Jianqiao1234ORCID,Liang Fei56748,Zhang Shiyan1234,Wu Yuandong1234,Sun Congting9106114ORCID,Xue Dongfeng9106114ORCID,Lin Zheshuai56748

Affiliation:

1. College of Chemistry and Chemical Engineering

2. Shanghai University of Engineering Science

3. Shanghai 201620

4. China

5. Technical Institute of Physics and Chemistry

6. Chinese Academy of Sciences

7. Beijing 100190

8. University of Chinese Academy of Sciences

9. State Key Laboratory of Rare Earth Resource Utilization

10. Changchun Institute of Applied Chemistry

11. Changchun 130022

Abstract

Inspired by the oxide SrB4O7with the largest known band gap among all borate crystals, the chalcogenide BaAl4S7with similar structure may possess attractive NLO properties.

Funder

National Natural Science Foundation of China

Shanghai University of Engineering and Science

Shanghai Municipal Education Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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