Gold dipyrrin-bisphenolates: a combined experimental and DFT study of metal–ligand interactions-Reference-Cited by-同舟云学术

Gold dipyrrin-bisphenolates: a combined experimental and DFT study of metal–ligand interactions

Published:2020 Issue:1 Volume:10 Page:533-540
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Thomas Kolle E.¹²³⁴,Desbois Nicolas⁵⁶⁷⁸⁹,Conradie Jeanet¹²³⁴¹^ORCID,Teat Simon J.¹⁰¹¹¹²¹³^ORCID,Gros Claude P.⁵⁶⁷⁸⁹^ORCID,Ghosh Abhik¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. UiT – The Arctic University of Norway

3. Tromsø N-9037

4. Norway

5. Institut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB)

6. UMR CNRS 6302

7. Université Bourgogne-Franche Comté

8. 21078 Dijon Cedex

9. France

10. Advanced Light Source

11. Lawrence Berkeley National Laboratory

12. Berkeley

13. USA

Abstract

The first gold dipyrrin-bisphenolates have been synthesized. Like their corrole analogues, they exhibit Au^III–L³⁻ ground states, providing rare innocent paradigms for a class of complexes that commonly occur as metalloradicals.

Funder

Centre National de la Recherche Scientifique

Norges Forskningsråd

European Regional Development Fund

National Research Foundation

Conseil régional de Bourgogne-Franche-Comté

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/RA/C9RA09228E

Reference66 articles.

1. Ligand Noninnocence in Cobalt Dipyrrin–Bisphenols: Spectroscopic, Electrochemical, and Theoretical Insights Indicating an Emerging Analogy with Corroles

2. The Structural Chemistry of Metallocorroles: Combined X-ray Crystallography and Quantum Chemistry Studies Afford Unique Insights

3. Electronic Structure of Corrole Derivatives: Insights from Molecular Structures, Spectroscopy, Electrochemistry, and Quantum Chemical Calculations

4. Seven Clues to Ligand Noninnocence: The Metallocorrole Paradigm

5. Metal complexes of corrole

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