Ligand Noninnocence in Cobalt Dipyrrin–Bisphenols: Spectroscopic, Electrochemical, and Theoretical Insights Indicating an Emerging Analogy with Corroles-Reference-Cited by-同舟云学术

Ligand Noninnocence in Cobalt Dipyrrin–Bisphenols: Spectroscopic, Electrochemical, and Theoretical Insights Indicating an Emerging Analogy with Corroles

Published:2019-01-17 Issue:12 Volume:58 Page:7677-7689
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Shan Wenqian¹,Desbois Nicolas²,Pacquelet Sandrine²,Stéphane Brandès ²^ORCID,Rousselin Yoann²,Conradie Jeanet³^ORCID,Ghosh Abhik⁴^ORCID,Gros Claude P.²^ORCID,Kadish Karl M.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Houston, Houston, Texas 77204-5003, United States

2. Institut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB), UMR CNRS 6302, Université de Bourgogne-Franche-Comté, 9 avenue Alain Savary, B.P. 47870, 21078 Dijon, Cedex, France

3. Department of Chemistry, University of the Free State, Bloemfontein 9300, Republic of South Africa

4. Department of Chemistry, UiT—The Arctic University of Norway, Tromsø N-9037, Norway

Funder

Welch Foundation

European Regional Development Fund

Centre National de la Recherche Scientifique

Conseil Regional de Bourgogne

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.8b03006

Reference34 articles.

1. Ligand-Centered Redox Activity in Cobalt(II) and Nickel(II) Bis(phenolate)-Dipyrrin Complexes

2. Co(III) complexes of tetradentate X3L type ligands: Synthesis, electronic structure, and reactivity

3. Electronic Structure and Reactivity of One-Electron-Oxidized Copper(II) Bis(phenolate)–Dipyrrin Complexes

4. Stable neutral radicals of planar N2O2-type dipyrrin platinum complexes: hybrid radicals of the delocalized organic π-orbital and platinum d-orbital

5. The structure of a one-electron oxidized Mn(iii)-bis(phenolate)dipyrrin radical complex and oxidation catalysis control via ligand-centered redox activity

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