Electrocatalytic water oxidation by copper(ii) complexes with a pentadentate amine-pyridine ligand

Author:

Lin Junqi1ORCID,Wang Nini1,Chen Xin1,Yang Xueli1,Hong Li1,Ruan Zhijun1ORCID,Ye Hui1,Chen Yanmei1,Liang Xiangming2

Affiliation:

1. Hubei Key Laboratory of Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University, Huanggang, 438000, China

2. Institute for New Energy Materials & Low Carbon Technologies, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, China

Abstract

Two Cu complexes are capable of catalyzing water oxidation. Oxygen evolution mediated by the Cu complex with a three –NH coordination environment occurs at low onset overpotential, while one –NCH3 group on the ligand would lead to lower activity.

Funder

Natural Science Foundation of Hubei Province

National Natural Science Foundation of China

Huanggang Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

Energy Engineering and Power Technology,Fuel Technology,Renewable Energy, Sustainability and the Environment

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