Improvement of electrocatalytic water oxidation activity of novel copper complex by modulating the axial coordination of phosphate on metal center-Reference-Cited by-同舟云学术

Improvement of electrocatalytic water oxidation activity of novel copper complex by modulating the axial coordination of phosphate on metal center

Published:2024 Issue:11 Volume:53 Page:5222-5229
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wang Jieying¹,Ping Yezi¹,Chen Yanmei¹,Liu Shanshan¹^ORCID,Dong Jinfeng¹,Ruan Zhijun¹^ORCID,Liang Xiangming²,Lin Junqi¹^ORCID

Affiliation:

1. Hubei Key Laboratory of Processing and Application of Catalytic Materials, College of Chemistry and Chemical Engineering, Huanggang Normal University, Huanggang 438000, China

2. School of Basic Medical Sciences, Ningxia Medical University, Yinchuan 750004, China

Abstract

Two Cu complexes were studied as electrocatalyst for water oxidation. Experiment and theoretical research indicate that the tertiary amine-coordinated structure abates the coordination of phosphate anion on Cu center and benefits oxygen evolution.

Funder

Huanggang Normal University

National Natural Science Foundation of China

Natural Science Foundation of Hubei Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT03409G

Reference50 articles.

1. Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation

2. Design of molecular water oxidation catalysts with earth-abundant metal ions

3. O–O bond formation mechanisms during the oxygen evolution reaction over synthetic molecular catalysts

4. Intramolecular hydroxyl nucleophilic attack pathway by a polymeric water oxidation catalyst with single cobalt sites

5. Molecular Nature of Electrodeposits in Electrochemical Water Oxidation

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