Structures and stability of AnO4 isomers, An = Pu, Am, and Cm: a relativistic density functional study-Reference-Cited by-同舟云学术

Structures and stability of AnO4 isomers, An = Pu, Am, and Cm: a relativistic density functional study

Published:2014 Issue:19 Volume:16 Page:8997-9001
ISSN:1463-9076
Container-title:Phys. Chem. Chem. Phys.
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Zaitsevskii Andréi¹²³⁴,Schwarz W. H. Eugen⁵⁶⁷⁸⁹

Affiliation:

1. NRC “Kurchatov Institute”

2. Moscow 123182, Russia

3. Petersburg Nuclear Physics Institute

4. St.-Petersburg District 188300, Russia

5. Department of Chemistry

6. Tsinghua University

7. Beijing 100084, China

8. Theoretical Chemistry

9. University Siegen

Abstract

The most stable oxidation state of the tetra-oxo-actinides decreases from U(vi) to Pu(v), Np(v), and Cm(v), preferentially forming actinyl-superoxides.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CP/C4CP00235K

Reference22 articles.

1. N. N. Krot , A. D.Gelman , M. P.Mefod'eva , V. P.Shilov , V. F.Peretrukhin and V. I.Spitsyn , Heptavalent State of Neptunium, Plutonium and Americium, UCRL-Trans-11798 , Lawrence Livermore National Laboratory , Livermore , 1977

2. Refinement of data on the volatility of octavalent plutonium in the form of tetraoxide PuO4

3. Thermochromatographic studies of plutonium oxides

4. Plutonium volatility in ozonization of alkaline solutions of Pu(VI) hydroxo complexes

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