Molecular oxides of high-valent actinides

Abstract

AbstractThe past decade has been very productive in the field of actinide (An) oxides containing high-valent An. Novel gas-phase experimental and an impressive number of theoretical studies have been performed, mostly on pure oxides or oxides extended with other ligands. The review covers the structural properties of molecular An oxides with high (An≥V) oxidation states. The presented compounds include the actinide dioxide cations [AnO2]+ and [AnO2]2+, neutral and ionic AnOx (x = 3–6), oxides with more than one An atom like neutral dimers, trimers and dimers from cation–cation interactions, as well as large U-oxide clusters observed very recently in the gaseous phase.