A discrete CuII6 cluster and a 3D MnII–CuII framework based on assembly of Mn2Cu4 clusters: synthesis, structure and magnetic properties

Author:

Chakraborty Anindita12345,Escuer Albert6789,Ribas Joan6789,Maji Tapas Kumar12345

Affiliation:

1. Molecular Materials Laboratory

2. Chemistry and Physics of Materials Unit

3. Jawaharlal Nehru Centre for Advanced Scientific Research

4. Bangalore 560 064

5. India

6. Departament de Quimica Inorganica

7. Universitat de Barcelona

8. 08028 Barcelona

9. Spain

Abstract

Two new magnetic metal–organic coordination compounds, a 0D Cu6 cluster and a 3D heterometallic framework with MnII2CuII4 secondary building units are synthesized. Detailed magnetic studies are performed with proper magneto-structural correlation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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