Pentanuclear MII–MnII (M = Ni and Cu) complexes of N2O2 donor ligands with a variation of carboxylate anions: syntheses, structures, magnetic properties and catecholase-like activities-Reference-Cited by-同舟云学术

Pentanuclear M^II–Mn^II (M = Ni and Cu) complexes of N₂O₂ donor ligands with a variation of carboxylate anions: syntheses, structures, magnetic properties and catecholase-like activities

Published:2022 Issue:36 Volume:46 Page:17260-17271
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Ganguly Sayantan¹²,Bhunia Pradip¹,Mayans Júlia³^ORCID,Ghosh Ashutosh¹⁴^ORCID

Affiliation:

1. Department of Chemistry, University College of Science, University of Calcutta, 92, A. P. C. Road, Kolkata 700 009, India

2. Department of Chemistry, Taki Government College, Taki, Hasnabad, West Bengal 743429, India

3. Departament de Química Inorgànica i Orgànica and Institut de Nanociència i Nanotecnologia (IN2UB), Universitat de Barcelona (UB), Martí iFranqués 1-11, Barcelona 08028, Spain

4. Rani Rashmoni Green University, Tarakeswar, Hooghly 712410, West Bengal, India

Abstract

One NiII2MnII3 and two CuII2MnII3 complexes have been synthesized using N2O2 donor ligands. The former complex exhibits spin crossover at 2 K temperature. All the complexes exhibit catecholase-like activities.

Funder

University Grants Commission

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NJ/D2NJ02215J

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1. Heterometallic transition metal clusters and cluster-supported coordination polymers derived from Tp- and Tp*-based Mo(W) sulfido precursors

2. A discrete CuII6 cluster and a 3D MnII–CuII framework based on assembly of Mn2Cu4 clusters: synthesis, structure and magnetic properties