Mechanism of generation of closo-decaborato amidrazones. Intramolecular non-covalent B–H⋯π(Ph) interaction determines stabilization of the configuration around the amidrazone CN bond-Reference-Cited by-同舟云学术

Mechanism of generation of closo-decaborato amidrazones. Intramolecular non-covalent B–H⋯π(Ph) interaction determines stabilization of the configuration around the amidrazone CN bond

Published:2018 Issue:11 Volume:42 Page:8693-8703
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Burianova Valeria K.¹²³⁴^ORCID,Bolotin Dmitrii S.¹²³⁴^ORCID,Mikherdov Alexander S.¹²³⁴^ORCID,Novikov Alexander S.¹²³⁴^ORCID,Mokolokolo Pennie Petrus⁵⁶⁷⁸,Roodt Andreas⁵⁶⁷⁸^ORCID,Boyarskiy Vadim P.¹²³⁴^ORCID,Dar’in Dmitry¹²³⁴,Krasavin Mikhail¹²³⁴,Suslonov Vitalii V.⁹²¹⁰⁴^ORCID,Zhdanov Andrey P.¹¹¹²⁴,Zhizhin Konstantin Yu.¹¹¹²⁴,Kuznetsov Nikolay T.¹¹¹²⁴

Affiliation:

1. Institute of Chemistry

2. Saint Petersburg State University

3. Saint Petersburg 199034

4. Russian Federation

5. Department of Chemistry

6. University of the Free State

7. Bloemfontein 9300

8. South Africa

9. Center for X-ray Diffraction Studies

10. Saint Petersburg 198504

11. N. S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

12. Moscow 119991

Abstract

Three types of N(H)-nucleophiles were used to study the nucleophilic addition to the CN group of the 2-propanenitrilium closo-decaborate cluster giving N-closo-decaborato amidrazones.

Funder

Saint Petersburg State University

Russian Foundation for Basic Research

Universiteit van die Vrystaat

Sasol

National Research Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ01018H