Rapid synthesis of redox-active dodecaborane B12(OR)12 clusters under ambient conditions-Reference-Cited by-同舟云学术

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Rapid synthesis of redox-active dodecaborane B12(OR)12 clusters under ambient conditions

Published:2016 Issue:5 Volume:3 Page:711-717
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Wixtrom Alex I.¹²³³⁴,Shao Yanwu¹²³³⁴,Jung Dahee¹²³³⁴,Machan Charles W.¹²⁵⁶⁴,Kevork Shaunt N.¹²³³⁴,Qian Elaine A.¹²³³⁴,Axtell Jonathan C.¹²³³⁴,Khan Saeed I.¹²³³⁴,Kubiak Clifford P.¹²⁵⁶⁴,Spokoyny Alexander M.¹²³³⁴

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of California

3. Los Angeles

4. USA

5. San Diego

6. La Jolla

Abstract

We have developed a fast and efficient route to obtain perfunctionalized ether-linked alkyl and benzyl derivatives of the closo-[B₁₂(OH)₁₂]²⁻ icosahedral dodecaborate cluster via microwave-assisted synthesis.

Funder

National Science Foundation

National Institutes of Health

Air Force Office of Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/QI/C5QI00263J

Reference65 articles.

1. The Valence Structure of the Boron Hydrides

2. The electronic structure of an icosahedron of boron atoms

3. The Nature of Boron Hydride Solids1

4. THE ISOLATION OF THE ICOSAHEDRAL B12H12-2 ION

5. Molecular Orbitals in Some Boron Compounds

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1. Chemistry of three-dimensional icosahedral boron clusters anions: closo-dodecaborate (2-) [B12H12]2- and carba-closo-dodecaborate(-) [CB11H12]-;Coordination Chemistry Reviews;2024-10

2. Using Bulky Dodecaborane-Based Dopants to Produce Mobile Charge Carriers in Amorphous Semiconducting Polymers;Chemistry of Materials;2024-05-17

3. Redox-Active Boron Clusters;Accounts of Chemical Research;2024-04-15

4. Carrier density and delocalization signatures in doped carbon nanotubes from quantitative magnetic resonance;Nanoscale Horizons;2024

5. Electrochemical Cycling of Redox-Active Boron Cluster-Based Materials in the Solid State;Journal of the American Chemical Society;2023-06-23

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