Dynamic effects on ligand field from rapid hydride motion in an iron(<scp>ii</scp>) dimer with an<i>S</i>= 3 ground state-Reference-Cited by-同舟云学术

Dynamic effects on ligand field from rapid hydride motion in an iron(ii) dimer with anS= 3 ground state

Published:2023 Issue:9 Volume:14 Page:2303-2312
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

McWilliams Sean F.¹,Mercado Brandon Q.¹^ORCID,MacLeod K. Cory¹^ORCID,Fataftah Majed S.¹,Tarrago Maxime²,Wang Xiaoping³^ORCID,Bill Eckhard²,Ye Shengfa²⁴^ORCID,Holland Patrick L.¹^ORCID

Affiliation:

1. Department of Chemistry, Yale University, New Haven, Connecticut, USA

2. Max Planck Institute for Chemical Energy Conversion, Mülheim an der Ruhr, Germany

3. Neutron Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, Tennessee, USA

4. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China

Abstract

Crystallographic, spectroscopic, and computational studies on diiron(ii) hydride complexes reveal rapid hydride motions that cause major changes in the electronic structures of the iron sites.

Funder

National Institute of General Medical Sciences

U.S. Department of Energy

Alexander von Humboldt-Stiftung

National Natural Science Foundation of China

Max-Planck-Förderstiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D2SC06412J