Iron(ii) and cobalt(ii) complexes based on anionic phenanthroline-imidazolate ligands: reversible single-crystal-to-single-crystal transformations
Author:
Affiliation:
1. Laboratoire MOLTECH-Anjou UMR 6200
2. UFR Sciences
3. CNRS
4. Université d'Angers
5. 49045 Angers
6. Departamento de Química Inorgánica
7. Instituto de Ciencia Molecular (ICMol)
8. Parque Científico
9. Universidad de Valencia
10. 46980 Paterna
Abstract
Among the series of FeII and CoII complexes based on phenanthroline-imidazolate ligands, the FeII complex (H9O4)[Fe(PIMP)3]·(C4H10O)2(H2O) (1a) exhibits reversible single-crystal-to-single-crystal transformations by solvent uptake/release.
Funder
Generalitat Valenciana
Ministerio de Economía y Competitividad
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CE/C8CE00561C
Reference72 articles.
1. Monitoring the crystallographic course of a single-crystal ? single-crystal photodimerization by X-ray diffractometry
2. Solvent diffusion through a non-porous crystal ‘caught in the act’ and related single-crystal-to-single-crystal transformations in a cationic dinuclear Ag(i) complex
3. Single-crystal-to-single-crystal transformations
4. Supramolecular structural transformations involving coordination polymers in the solid state
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