Solvent diffusion through a non-porous crystal ‘caught in the act’ and related single-crystal-to-single-crystal transformations in a cationic dinuclear Ag(i) complex-Reference-Cited by-同舟云学术

Solvent diffusion through a non-porous crystal ‘caught in the act’ and related single-crystal-to-single-crystal transformations in a cationic dinuclear Ag(i) complex

Published:2015 Issue:46 Volume:17 Page:8957-8964
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Alen Jo¹²³,Van Meervelt Luc¹²³,Dehaen Wim¹²³,Dobrzańska Liliana¹²³

Affiliation:

1. Department of Chemistry

2. Katholieke Universiteit Leuven

3. 3001 Heverlee, Belgium

Abstract

A few snapshots of a dynamic solvent diffusion process through a seemingly non-porous crystal of a dinuclear, cyclic Ag(i) complex were revealed. These indicate the complexity of the process, which involves not only relocation of the molecules in the crystal lattice, but also conformational adjustments of the metallocycles in response to solvent uptake/release.

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CE/C5CE01348H

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