Insights into mechanisms of diphosphine-mediated controlled surface construction on Au nanoclusters-Reference-Cited by-同舟云学术

Insights into mechanisms of diphosphine-mediated controlled surface construction on Au nanoclusters

Published:2022 Issue:42 Volume:14 Page:15804-15811
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Li Qinzhen¹,Yang Sha²^ORCID,Chai Jinsong²^ORCID,Zhang Hui¹^ORCID,Zhu Manzhou²^ORCID

Affiliation:

1. School of Materials Science and Engineering, Anhui University, Hefei, Anhui 230601, China

2. Department of Chemistry and Centre for Atomic Engineering of Advanced Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Institutes of Physical Science and Information Technology and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials, Anhui University, Hefei, Anhui 230601, China

Abstract

Controlled diphosphine-mediated surface modification on Au23(SR)16− nanoclusters is realized. Mechanistic study shows that the size of the resulting nanoclusters can be controlled by tuning the length and configuration of diphosphines.

Funder

Ministry of Education of the People's Republic of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2022/NR/D2NR05291A

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1. Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities

2. Atomically Precise Clusters of Noble Metals: Emerging Link between Atoms and Nanoparticles