Site-selective redox isomerizations of furanosides using a combined arylboronic acid/photoredox catalyst system-Reference-Cited by-同舟云学术

Site-selective redox isomerizations of furanosides using a combined arylboronic acid/photoredox catalyst system

Published:2020 Issue:6 Volume:11 Page:1531-1537
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Dimakos Victoria¹²³⁴,Gorelik Daniel¹²³⁴,Su Hsin Y.¹²³⁴,Garrett Graham E.¹²³⁴^ORCID,Hughes Gregory⁵⁶⁷⁸,Shibayama Hiromitsu¹²³⁴,Taylor Mark S.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Toronto

3. Toronto

4. Canada

5. Global Process Chemistry

6. Merck Research Laboratories

7. Rahway

8. USA

Abstract

The combined action of boronic acid, photoredox catalyst and hydrogen atom transfer mediator enables the transformation of furanosides to 2-keto-3-deoxyfuranosides, a synthetic analog of the process catalyzed by the ribonucleotide reductase enzymes.

Funder

Compute Canada

Natural Sciences and Engineering Research Council of Canada

McLean Foundation

Canada Foundation for Innovation

Kyoto University

University of Toronto

Government of Ontario

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry