Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindoles-Reference-Cited by-同舟云学术

Palladium-catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O2: a facile protocol to selectively synthesize 2- and 3-vinylindoles

Published:2017 Issue:1 Volume:53 Page:216-219
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Cao Bo¹²³⁴⁵,Simaan Marwan⁶⁷⁸⁹¹⁰^ORCID,Marek Ilan⁶⁷⁸⁹¹⁰,Wei Yin¹¹¹²¹³¹⁴¹⁵,Shi Min¹²³⁴⁵

Affiliation:

1. Key Laboratory for Advanced Materials and Institute of Fine Chemicals

2. School of Chemistry & Molecular Engineering

3. East China University of Science and Technology

4. Shanghai 200237

5. China

6. The Mallat Family Laboratory of Organic Chemistry

7. Schulich Faculty of Chemistry and Lise Meitner-Minerva Center for Computational Quantum Chemistry

8. Technion-Israel Institute of Technology

9. Technion City

10. Israel

11. State Key Laboratory of Organometallic Chemistry

12. University of Chinese Academy of Sciences

13. Shanghai Institute of Organic Chemistry

14. Chinese Academy of Sciences

15. Shanghai 200032

Abstract

A facile and versatile palladium catalyzed oxidative cyclization of aniline-tethered alkylidenecyclopropanes with O₂ to selectively construct important synthetic intermediates 2- and 3-vinylindoles in moderate to good yields has been developed.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C6CC08731K

Reference87 articles.

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3. R. J. Sundberg , Indoles, Academic Press, San Diego, 1996

4. Indolizidine and quinolizidine alkaloids

5. Marine natural products

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