Iron(iii) and cobalt(iii) complexes with both tautomeric (keto and enol) forms of aroylhydrazone ligands: catalysts for the microwave assisted oxidation of alcohols-Reference-Cited by-同舟云学术

Iron(iii) and cobalt(iii) complexes with both tautomeric (keto and enol) forms of aroylhydrazone ligands: catalysts for the microwave assisted oxidation of alcohols

Published:2016 Issue:10 Volume:6 Page:8079-8088
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Sutradhar Manas¹²³⁴⁵,Alegria Elisabete C. B. A.¹²³⁴⁵^ORCID,Mahmudov Kamran T.¹²³⁴⁵,Guedes da Silva M. Fátima C.¹²³⁴⁵,Pombeiro Armando J. L.¹²³⁴⁵

Affiliation:

1. Centro de Química Estrutural

2. Instituto Superior Técnico

3. Universidade de Lisboa

4. 1049-001 Lisboa

5. Portugal

Abstract

Aroylhydrazone Fe(iii) and Co(iii) complexes of both keto and enol tautomeric forms of the ligand are reported and shown to catalyze the microwave-assisted solvent-free peroxidative oxidation (by TBHP) of primary and secondary alcohols.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA25774C

Reference72 articles.

1. Coordination chemistry of arylhydrazones of methylene active compounds

2. Coordination chemistry of non-oxido, oxido and dioxidovanadium(IV/V) complexes with azine fragment ligands

3. Tautomeric effect of hydrazone Schiff bases in tetranuclear Cu(ii) complexes: magnetism and catalytic activity towards mild hydrocarboxylation of alkanes