Affiliation:
1. Department of Science and Applied Technology, Politecnico di Torino, Corso Duca degli Abruzzi 24, I-10129 Torino, Italy
2. Department of Chemical Sciences, Università degli Studi di Napoli Federico II, Via Cinthia, I-80126 Napoli, Italy
Abstract
Among N-rich heterocycle backbone compounds, the triazoles building block received a lot of interest in several different academic and industrial studies and applications. This article outlines the process of synthesizing three different 1,2,4-triazole-based systems, commencing with 1,3-diaminoguanidine hydrochloride monohydrate as the starting material. The five novel crystal structures, Triaz1, Triaz2, Triaz3, Triaz4, and Triaz5, were characterized by NMR spectroscopy and single-crystal X-ray diffraction analysis. Hirshfeld surface analysis was employed to explore the intermolecular interactions that are responsible for quantitative crystal packing. The synthesized compounds, with their elevated nitrogen content, serve as potential components for High-Energy-Density material science applications.
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering