Preferential binding of unsaturated hydrocarbons in aryl-bisimidazolium·cucurbit[8]uril complexes furbishes evidence for small-molecule π–π interactions

Author:

Barrow Steven J.12345ORCID,Assaf Khaleel I.6789ORCID,Palma Aniello12345,Nau Werner M.6789ORCID,Scherman Oren A.12345ORCID

Affiliation:

1. Melville Laboratory for Polymer Synthesis

2. Department of Chemistry

3. University of Cambridge

4. Cambridge

5. UK

6. Department of Life Sciences and Chemistry

7. Jacobs University Bremen

8. D-28759 Bremen

9. Germany

Abstract

Restricting the internal cavity size of cucurbit[8]uril with auxiliary guests sets up an intermolecular interaction chamber for hydrocarbons, which provides insights into dispersion, arene–hydrocarbon interactions, and desolvation effects.

Funder

Deutsche Forschungsgemeinschaft

H2020 Marie Skłodowska-Curie Actions

Engineering and Physical Sciences Research Council

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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