Valence tautomerism and spin crossover in pyridinophane–cobalt–dioxolene complexes: an experimental and computational study

Author:

Tezgerevska Tina1234,Rousset Elodie1234ORCID,Gable Robert W.1234ORCID,Jameson Guy N. L.1234ORCID,Sañudo E. Carolina56789ORCID,Starikova Alyona10111213ORCID,Boskovic Colette1234ORCID

Affiliation:

1. School of Chemistry

2. University of Melbourne

3. Melbourne

4. Australia

5. Departament de Química Inorgànica i Orgànica

6. Universitat de Barcelona

7. 08028 Barcelona

8. Spain

9. Institut de Nanociència i Nanotecnologia

10. Institute of Physical and Organic Chemistry

11. Southern Federal University

12. 344090 Rostov on Don

13. Russian Federation

Abstract

Variation of alkyl substituents on pyridinophane ancillary ligands governs temperature-dependent valence tautomeric or spin crossover equilibria in a family of cobalt–dioxolene complexes.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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