Tuning valence tautomerism in a family of dinuclear cobalt complexes incorporating a conjugated bridging bis(dioxolene) ligand with weak communication-Reference-Cited by-同舟云学术

Tuning valence tautomerism in a family of dinuclear cobalt complexes incorporating a conjugated bridging bis(dioxolene) ligand with weak communication

Published:2024 Issue:7 Volume:53 Page:3104-3117
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fischer Tristan E.¹,Janetzki Jett T.¹^ORCID,M. Zahir F. Zahra¹^ORCID,Gable Robert W.¹^ORCID,Starikova Alyona A.²^ORCID,Boskovic Colette¹^ORCID

Affiliation:

1. School of Chemistry, University of Melbourne, Parkville, 3010 Victoria, Australia

2. Institute of Physical and Organic Chemistry, Southern Federal University, 344090, Rostov-on-Don, Russian Federation

Abstract

Judicious pairing of ancillary and redox-active ligands affords thermally-induced two-step valence tautomerism for a dinuclear cobalt complex bridged by a conjugated bis(dioxolene) ligand.

Funder

University of Melbourne

Ministry of Science and Higher Education of the Russian Federation

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT04162J

Reference56 articles.

1. Valence tautomerism in metal complexes: Stimulated and reversible intramolecular electron transfer between metal centers and organic ligands

2. Opto-Spintronics: Photoisomerization-Induced Spin State Switching at 300 K in Photochrome Cobalt–Dioxolene Thin Films

3. Quinonoid Metal Complexes: Toward Molecular Switches

4. Molecular magnetism: from chemical design to spin control in molecules, materials and devices

5. A Three-State Surface-Confined Molecular Switch with Multiple Channel Outputs

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