“Low-coordinate” 1,2-oxaphosphetanes – a new opportunity in coordination and main group chemistry-Reference-Cited by-同舟云学术

“Low-coordinate” 1,2-oxaphosphetanes – a new opportunity in coordination and main group chemistry

Published:2018 Issue:52 Volume:54 Page:7123-7126
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Kyri A. W.¹²³⁴^ORCID,Gleim F.¹²³⁴,García Alcaraz A.⁵⁶⁷⁸⁹,Schnakenburg G.¹²³⁴,Espinosa Ferao A.⁵⁶⁷⁸⁹^ORCID,Streubel R.¹²³⁴^ORCID

Affiliation:

1. Institut für Anorganische Chemie der

2. Rheinischen Friedrich-Wilhelms-Universität Bonn

3. 53121 Bonn

4. Germany

5. Facultad de Química

6. Campus de Espinardo

7. Universidad de Murcia

8. 30100 Murcia

9. Spain

Abstract

While 1,2σ⁵λ⁵-oxaphosphetanes are well known intermediates from the Wittig-reaction, no 1,2σ³λ³-oxaphosphetanes have been described, so far. First investigations towards metal coordination and P-oxidation, as well as DFT calculations on retro-[2+2] cycloaddition reactions of the 1,2-oxaphosphetane ring are presented.

Funder

European Cooperation in Science and Technology

Rheinische Friedrich-Wilhelms-Universität Bonn

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC02963F

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