Arbuzov meets 1,2-oxaphosphetanes: transient 1,2-oxaphosphetan-2-iums as an entry point to beta-halo phosphane oxides and P-containing oligomers

Author:

Gleim Florian1,Schnakenburg Gregor1ORCID,Ferao Arturo Espinosa2ORCID,Streubel Rainer1ORCID

Affiliation:

1. Institut für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhardt-Domagk-Straße 1, 53121 Bonn, Germany

2. Facultad de Química, Campus de Espinardo, Universidad de Murcia, 30100 Murcia, Spain

Abstract

Where to go? Synthesis and reactions of a C-unsubstituted 1,2σ3λ3-oxaphosphetane with alkyl halides are described, forming β-halo phosphane oxides in an Arbuzov-type reaction. In the case of methyl triflate, oligomerization was observed.

Funder

Universidad de Murcia

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

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