Arbuzov meets 1,2-oxaphosphetanes: transient 1,2-oxaphosphetan-2-iums as an entry point to beta-halo phosphane oxides and P-containing oligomers-Reference-Cited by-同舟云学术

Arbuzov meets 1,2-oxaphosphetanes: transient 1,2-oxaphosphetan-2-iums as an entry point to beta-halo phosphane oxides and P-containing oligomers

Published:2024 Issue:19 Volume:60 Page:2625-2628
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Gleim Florian¹,Schnakenburg Gregor¹^ORCID,Ferao Arturo Espinosa²^ORCID,Streubel Rainer¹^ORCID

Affiliation:

1. Institut für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Gerhardt-Domagk-Straße 1, 53121 Bonn, Germany

2. Facultad de Química, Campus de Espinardo, Universidad de Murcia, 30100 Murcia, Spain

Abstract

Where to go? Synthesis and reactions of a C-unsubstituted 1,2σ3λ3-oxaphosphetane with alkyl halides are described, forming β-halo phosphane oxides in an Arbuzov-type reaction. In the case of methyl triflate, oligomerization was observed.

Funder

Universidad de Murcia

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC00254G

Reference40 articles.

1. Small Inorganic Rings in the 21st Century: From Fleeting Intermediates to Novel Isolable Entities

2. Oxetanes: Recent Advances in Synthesis, Reactivity, and Medicinal Chemistry

3. Aliphatic Polyethers: Classical Polymers for the 21st Century

4. Synthesis and Properties of Phosphetanes

5. A Phosphetane Catalyzes Deoxygenative Condensation of α-Keto Esters and Carboxylic Acids via PIII/PV═O Redox Cycling

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