Neutral and cationic phosphine and arsine complexes of tin(iv) halides: synthesis, properties, structures and anion influence

Author:

Greenacre Victoria K.1234,King Rhys P.1234,Levason William1234ORCID,Reid Gillian1234ORCID

Affiliation:

1. School of Chemistry

2. University of Southampton

3. Southampton SO17 1BJ

4. UK

Abstract

A series of tin(iv) halide complexes with mono- and bidentate pnictine ligands and the influence of various halide abstractors on these is discussed, together with DFT calculations to probe the HOMO/LUMO energies in the resulting species.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference38 articles.

1. Comprehensive Coordination Chemistry , ed. G. Wilkinson , J. A. McCleverty and R. D. Gillard , Pergamon , Oxford , 1988

2. Comprehensive Coordination Chemistry II , ed. J. A. McCleverty and T. J. Meyer , Elsevier , Oxford , 2004

3. P. G. Harrison , Comprehensive Coordination Chemistry , 1988 , 3 , 183

4. J. Parr , Comprehensive Coordination Chemistry II , 2004 , 3 , 545

5. The Chemistry of Tin , ed. P. J. Smith , Chapman & Hall , London , 1998

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